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空天防御  2024, Vol. 7 Issue (6): 128-134    
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  研究论文 本期目录 | 过刊浏览 | 高级检索 |
不同结构酚醛改性环氧树脂的力学性能及其对涂层摩擦磨损性能的影响
肖金涛,李洁琼,王姝书,沈曌隽,周天导,鞠鹏飞
上海航天设备制造总厂有限公司,上海 200245
Mechanical Properties of Phenolic Modified Epoxy Resins with Different Structures and Their Influence on the Friction and Wear Properties of Coatings
XIAO Jintao, LI Jieqiong, WANG Shushu, SHEN Zhaojun, ZHOU Tiandao, JU Pengfei
Shanghai Aerospace Equipments Manufacture Co., Ltd., Shanghai 200245, China
全文: PDF(1704 KB)  
输出: BibTeX | EndNote (RIS)      
摘要 为考察不同结构酚醛树脂改性环氧树脂的力学性能及对涂层摩擦磨损性能的影响,同时为设计高性能长寿命粘结固体润滑涂层提供理论支持,本文采用动态热机械性能测试(DMA)和V-block 摩擦磨损试验,分析改性环氧树脂(EP)/硼酚醛树脂(FBB)和环氧树脂(EP)/线性酚醛树脂(SG)交联密度与力学性能的关系,并考察不同交联密度树脂对涂层摩擦磨损性能的影响。研究表明,随着环氧树脂/酚醛树脂比例的增加,树脂交联密度逐渐减小,弹性模量先增加后减小。在比例为5∶1 时,弹性模量达到最大、耐磨寿命最长;线性酚醛(SG)改性环氧树脂(EP)在最大弹性模量时具有较低交联密度,形成的涂层具有更长耐磨寿命;通过合成具有适宜交联密度的树脂体系,可明显改善粘结固体润滑涂层的耐磨寿命,为开发具有更长寿命的高性能涂层提供科学依据。
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关键词 粘结固体润滑涂层树脂结构交联密度弹性模量摩擦磨损    
Abstract:To investigate the mechanical properties of phenolic resin-modified epoxy resin in different structures and their effects on the friction and wear coating properties, and acquire theoretical support for the design of highperformance, long-life bonded solid lubricating coatings, the relationship between crosslinking density and mechanical properties of modified epoxy resin (EP)/boron phenolic resin (FBB) and epoxy resin (EP)/linear phenolic resin (SG) was analyzed using dynamic thermomechanical property testing (DMA) and V-block friction and wear testing. The influence of different crosslinking density resins of the coating was also investigated. The results showed that when the ratio of epoxy resin/phenolic resin increases, the crosslinking density of the resin gradually decreases, while the elastic modulus first increases before it decreases. When the ratio is 5:1, the elastic modulus reaches its maximum, and the wear resistance life is the longest. Linear phenolic (SG) modified epoxy resin (EP) has a lower crosslink density at the maximum elastic modulus, resulting in a longer wear resistance life. A resin system with suitable crosslinking density can significantly improve the wear resistance life of coatings. By synthesizing resin systems with suitable cross-linking density, the wear resistance life of bonded solid lubricating coatings can be considerably enhanced, providing a scientific basis for developing high-performance coatings with longer life.
Key wordsbonding solid lubricating coating    resin structure    crosslinking density    elastic modulus    friction and wear
收稿日期: 2024-05-20      出版日期: 2025-01-16
ZTFLH:  TQ 323. 5  
基金资助:国家重点研发计划项目(2022YFB4600103)
通讯作者: 鞠鹏飞(1987—),男,博士,研究员。   
作者简介: 肖金涛(1994—),男,硕士,工程师。
引用本文:   
肖金涛, 李洁琼, 王姝书, 沈曌隽, 周天导, 鞠鹏飞. 不同结构酚醛改性环氧树脂的力学性能及其对涂层摩擦磨损性能的影响[J]. 空天防御, 2024, 7(6): 128-134.
XIAO Jintao, LI Jieqiong, WANG Shushu, SHEN Zhaojun, ZHOU Tiandao, JU Pengfei. Mechanical Properties of Phenolic Modified Epoxy Resins with Different Structures and Their Influence on the Friction and Wear Properties of Coatings. Air & Space Defense, 2024, 7(6): 128-134.
链接本文:  
https://www.qk.sjtu.edu.cn/ktfy/CN/      或      https://www.qk.sjtu.edu.cn/ktfy/CN/Y2024/V7/I6/128

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