Please wait a minute...
Nano-Micro Letters  2024, Vol. 16 Issue (1): 165-    DOI: 10.1007/s40820-024-01365-w
  本期目录 | 过刊浏览 | 高级检索 |
Shaodian Yang1, Zhiqiang Lin2, Ximiao Wang1,3, Junhua Huang1, Rongliang Yang1, Zibo Chen1, Yi Jia4, Zhiping Zeng5, Zhaolong Cao1,3, Hongjia Zhu1,3, Yougen Hu2, Enen Li6,7,8, Huanjun Chen1,3(), Tianwu Wang6,7,8(), Shaozhi Deng1,3(), Xuchun Gui1()
Stretchable, Transparent, and Ultra-Broadband Terahertz Shielding Thin Films Based on Wrinkled MXene Architectures
Shaodian Yang1, Zhiqiang Lin2, Ximiao Wang1,3, Junhua Huang1, Rongliang Yang1, Zibo Chen1, Yi Jia4, Zhiping Zeng5, Zhaolong Cao1,3, Hongjia Zhu1,3, Yougen Hu2, Enen Li6,7,8, Huanjun Chen1,3(), Tianwu Wang6,7,8(), Shaozhi Deng1,3(), Xuchun Gui1()
1 State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China
2 National Key Laboratory of Materials for Integrated Circuits, Shenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, People’s Republic of China
3 Guangdong Province Key Laboratory of Display Material and Technology, Guangzhou, 510275, People’s Republic of China
4 China Academy of Aerospace Science and Innovation, Beijing, 100176, People’s Republic of China
5 School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China
6 GBA Branch of Aerospace Information Research Institute, Chinese Academy of Sciences, Guangzhou, 510700, People’s Republic of China
7 School of Electronic, Electrical and Communication Engineering, University of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China
8 Guangdong Provincial Key Laboratory of Terahertz Quantum Electromagnetics, Guangzhou, 510700, People’s Republic of China
全文: PDF(2488 KB)   HTML
输出: BibTeX | EndNote (RIS)      
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
Shaodian Yang
Zhiqiang Lin
Ximiao Wang
Junhua Huang
Rongliang Yang
Zibo Chen
Yi Jia
Zhiping Zeng
Zhaolong Cao
Hongjia Zhu
Yougen Hu
Enen Li
Huanjun Chen
Tianwu Wang
Shaozhi Deng
Xuchun Gui
Abstract：

With the increasing demand for terahertz (THz) technology in security inspection, medical imaging, and flexible electronics, there is a significant need for stretchable and transparent THz electromagnetic interference (EMI) shielding materials. Existing EMI shielding materials, like opaque metals and carbon-based films, face challenges in achieving both high transparency and high shielding efficiency (SE). Here, a wrinkled structure strategy was proposed to construct ultra-thin, stretchable, and transparent terahertz shielding MXene films, which possesses both isotropous wrinkles (height about 50 nm) and periodic wrinkles (height about 500 nm). Compared to flat film, the wrinkled MXene film (8 nm) demonstrates a remarkable 36.5% increase in SE within the THz band. The wrinkled MXene film exhibits an EMI SE of 21.1 dB at the thickness of 100 nm, and an average EMI SE/t of 700 dB μm−1 over the 0.1-10 THz. Theoretical calculations suggest that the wrinkled structure enhances the film's conductivity and surface plasmon resonances, resulting in an improved THz wave absorption. Additionally, the wrinkled structure enhances the MXene films' stretchability and stability. After bending and stretching (at 30% strain) cycles, the average THz transmittance of the wrinkled film is only 0.5% and 2.4%, respectively. The outstanding performances of the wrinkled MXene film make it a promising THz electromagnetic shielding materials for future smart windows and wearable electronics.
Key words： Terahertz    Wrinkle structure    Electromagnetic interference shielding    MXene
收稿日期: 2023-11-22      出版日期: 2024-04-02
通讯作者: Huanjun Chen, Tianwu Wang, Shaozhi Deng, Xuchun Gui   
引用本文:   
Shaodian Yang, Zhiqiang Lin, Ximiao Wang, Junhua Huang, Rongliang Yang, Zibo Chen, Yi Jia, Zhiping Zeng, Zhaolong Cao, Hongjia Zhu, Yougen Hu, Enen Li, Huanjun Chen, Tianwu Wang, Shaozhi Deng, Xuchun Gui. [J]. Nano-Micro Letters, 2024, 16(1): 165-.
Shaodian Yang, Zhiqiang Lin, Ximiao Wang, Junhua Huang, Rongliang Yang, Zibo Chen, Yi Jia, Zhiping Zeng, Zhaolong Cao, Hongjia Zhu, Yougen Hu, Enen Li, Huanjun Chen, Tianwu Wang, Shaozhi Deng, Xuchun Gui. Stretchable, Transparent, and Ultra-Broadband Terahertz Shielding Thin Films Based on Wrinkled MXene Architectures. Nano-Micro Letters, 2024, 16(1): 165-.
链接本文:  
https://www.qk.sjtu.edu.cn/nml/CN/10.1007/s40820-024-01365-w      或      https://www.qk.sjtu.edu.cn/nml/CN/Y2024/V16/I1/165
Fig. 1  
Fig. 2  
Fig. 3  
Fig. 4  
Fig. 5  
1.
M. Samizadeh Nikoo, E. Matioli, Electronic metadevices for terahertz applications. Nature 614, 451-455 (2023).
2.
V. Pistore, H. Nong, P.-B. Vigneron, K. Garrasi, S. Houver et al., Millimeter wave photonics with terahertz semiconductor lasers. 2021 46th International Conference on Infrared, Millimeter and Terahertz Waves (IRMMW-THz). Chengdu, China. IEEE, (2021), pp1.
3.
L. Luo, I. Chatzakis, J. Wang, F.B.P. Niesler, M. Wegener et al., Broadband terahertz generation from metamaterials. Nat. Commun. 5, 3055 (2014).
4.
D. Suzuki, S. Oda, Y. Kawano, A flexible and wearable terahertz scanner. Nat. Photonics 10, 809-813 (2016).
5.
Y. Yu, P. Yi, W. Xu, X. Sun, G. Deng et al., Environmentally tough and stretchable MXene organohydrogel with exceptionally enhanced electromagnetic interference shielding performances. Nano-Micro Lett. 14, 77 (2022).
6.
Z.H. Zeng, N. Wu, J.J. Wei, Y.F. Yang, T.T. Wu et al., Porous and ultra-flexible crosslinked MXene/polyimide composites for multifunctional electromagnetic interference shielding. Nano-Micro Lett. 14, 59 (2022).
7.
B. Shi, P. Wang, J. Feng, C. Xue, G. Yang et al., Split-ring structured all-inorganic perovskite photodetector arrays for masterly Internet of Things. Nano-Micro Lett. 15, 3 (2022).
8.
M. Kutas, B. Haase, P. Bickert, F. Riexinger, D. Molter et al., Terahertz quantum sensing. Sci. Adv. 6, eaaz8065 (2020).
9.
M. Manjappa, A. Solanki, A. Kumar, T.C. Sum, R. Singh, Solution-processed lead iodide for ultrafast all-optical switching of terahertz photonic devices. Adv. Mater. 31, e1901455 (2019).
10.
A.G. Markelz, D.M. Mittleman, Perspective on terahertz applications in bioscience and biotechnology. ACS Photonics 9, 1117-1126 (2022).
11.
M. Chen, Y. Wang, Z. Zhao, Monolithic metamaterial-integrated graphene terahertz photodetector with wavelength and polarization selectivity. ACS Nano 16, 17263-17273 (2022).
12.
Y. Ghasempour, R. Shrestha, A. Charous, E. Knightly, D.M. Mittleman, Single-shot link discovery for terahertz wireless networks. Nat. Commun. 11, 2017 (2020).
13.
R. Yang, X. Gui, L. Yao, Q. Hu, L. Yang et al., Ultrathin, lightweight, and flexible CNT buckypaper enhanced using MXenes for electromagnetic interference shielding. Nano-Micro Lett. 13, 66 (2021).
14.
R.B. Schulz, V.C. Plantz, D.R. Brush, Shielding theory and practice. IEEE Trans. Electromagn. Compat. 30, 187-201 (1988).
15.
N. van Hoof, M. Parente, A. Baldi, J.G. Rivas, Terahertz time-domain spectroscopy and near-field microscopy of transparent silver nanowire networks. Adv. Opt. Mater. 8, 1900790 (2020).
16.
S. Hou, W. Ma, G. Li, Y. Zhang, Y. Ji et al., Excellent Terahertz shielding performance of ultrathin flexible Cu/graphene nanolayered composites with high stability. J. Mater. Sci. Technol. 52, 136-144 (2020).
17.
B. Zhao, Z. Bai, H. Lv, Z. Yan, Y. Du et al., Self-healing liquid metal magnetic hydrogels for smart feedback sensors and high-performance electromagnetic shielding. Nano-Micro Lett. 15, 79 (2023).
18.
H. Duan, H. Zhu, J. Gao, D.-X. Yan, K. Dai et al., Asymmetric conductive polymer composite foam for absorption dominated ultra-efficient electromagnetic interference shielding with extremely low reflection characteristics. J. Mater. Chem. A 8, 9146-9159 (2020).
19.
J. Bang, J. Ahn, J. Zhang, T.H. Ko, B. Park et al., Stretchable and directly patternable double-layer structure electrodes with complete coverage. ACS Nano 16, 12134-12144 (2022).
20.
S. Park, J. Bang, B.-S. Kim, S.J. Oh, J.-H. Choi, Metallic fusion of nanocrystal thin films for flexible and high-performance electromagnetic interference shielding materials. Mater. Today Adv. 12, 100177 (2021).
21.
Y.I. Jhon, J.H. Lee, Y.M. Jhon, Surface termination effects on the terahertz-range optical responses of two-dimensional MXenes: density functional theory study. Mater. Today Commun. 32, 103917 (2022).
22.
L.-X. Liu, W. Chen, H.-B. Zhang, L. Ye, Z. Wang et al., Super-tough and environmentally stable aramid. Nanofiber@MXene coaxial fibers with outstanding electromagnetic interference shielding efficiency. Nano-Micro Lett. 14, 111 (2022).
23.
J. Wang, X. Ma, J. Zhou, F. Du, C. Teng, Bioinspired, high-strength, and flexible MXene/aramid fiber for electromagnetic interference shielding papers with joule heating performance. ACS Nano 16, 6700-6711 (2022).
24.
Y. Zhu, J. Liu, T. Guo, J.J. Wang, X. Tang et al., Multifunctional Ti3C2Tx MXene composite hydrogels with strain sensitivity toward absorption-dominated electromagnetic-interference shielding. ACS Nano 15, 1465-1474 (2021).
25.
H. Wan, N. Liu, J. Tang, Q. Wen, X. Xiao, Substrate-independent Ti3C2Tx MXene waterborne paint for terahertz absorption and shielding. ACS Nano 15, 13646-13652 (2021).
26.
T. Zhao, P. Xie, H. Wan, T. Ding, M. Liu et al., Ultrathin MXene assemblies approach the intrinsic absorption limit in the 0.5-10 THz band. Nat. Photonics 17, 622-628 (2023).
27.
V. Mauchamp, M. Bugnet, E.P. Bellido, G.A. Botton, P. Moreau et al., Enhanced and tunable surface plasmons in two-dimensional Ti3C2 stacks: electronic structure versus boundary effects. Phys. Rev. B 89, 235428 (2014).
28.
Q. Zou, W. Guo, L. Zhang, L. Yang, Z. Zhao et al., MXene-based ultra-thin film for terahertz radiation shielding. Nanotechnology 31, 505710 (2020).
29.
A. Iqbal, P. Sambyal, C.M. Koo, 2D MXenes for electromagnetic shielding: a review. Adv. Funct. Mater. 30, 2000883 (2020).
30.
T. Yun, H. Kim, A. Iqbal, Y.S. Cho, G.S. Lee et al., Electromagnetic shielding of monolayer MXene assemblies. Adv. Mater. 32, e1906769 (2020).
31.
J.T. Hong, D.J. Park, J.Y. Moon, S.B. Choi, J.K. Park et al., Terahertz wave applications of single-walled carbon nanotube films with high shielding effectiveness. Appl. Phys. Express 5, 015102 (2012).
32.
G. Li, N. Amer, H.A. Hafez, S. Huang, D. Turchinovich et al., Dynamical control over terahertz electromagnetic interference shielding with 2D Ti3C2Ty MXene by ultrafast optical pulses. Nano Lett. 20, 636-643 (2020).
33.
G. Choi, F. Shahzad, Y.-M. Bahk, Y.M. Jhon, H. Park et al., Enhanced terahertz shielding of MXenes with nano-metamaterials. Adv. Opt. Mater. 6, 1701076 (2018).
34.
B. Zhao, Y. Du, Z. Yan, L. Rao, G. Chen et al., Structural defects in phase-regulated high-entropy oxides toward superior microwave absorption properties. Adv. Funct. Mater. 33, 2209924 (2023).
35.
Y. Du, Z. Yan, W. You, Q. Men, G. Chen et al., Balancing MXene surface termination and interlayer spacing enables superior microwave absorption. Adv. Funct. Mater. 33, 2301449 (2023).
36.
B. Zhao, Z. Yan, Y. Du, L. Rao, G. Chen et al., High-entropy enhanced microwave attenuation in titanate perovskites. Adv. Mater. 35, e2210243 (2023).
37.
J. Li, H. Sun, S.-Q. Yi, K.-K. Zou, D. Zhang et al., Flexible polydimethylsiloxane composite with multi-scale conductive network for ultra-strong electromagnetic interference protection. Nano-Micro Lett. 15, 15 (2022).
38.
Z. Zhang, S. Yang, P. Zhang, J. Zhang, G. Chen et al., Mechanically strong MXene/Kevlar nanofiber composite membranes as high-performance nanofluidic osmotic power generators. Nat. Commun. 10, 2920 (2019).
39.
R. Yang, H. Song, Z. Zhou, S. Yang, X. Tang et al., Ultra-sensitive, multi-directional flexible strain sensors based on an MXene film with periodic wrinkles. ACS Appl. Mater. Interfaces 15, 8345-8354 (2023).
40.
S. Yang, R. Yang, Z. Lin, X. Wang, S. Liu et al., Ultrathin, flexible, and high-strength polypyrrole/Ti3C2Tx film for wide-band gigahertz and terahertz electromagnetic interference shielding. J. Mater. Chem. A 10, 23570-23579 (2022).
41.
A. Javili, A.D. Bakiler, A displacement-based approach to geometric instabilities of a film on a substrate. Math. Mech. Solids 24, 2999-3023 (2019).
42.
B. Zhao, C.B. Park, Tunable electromagnetic shielding properties of conductive poly(vinylidene fluoride)/Ni chain composite films with negative permittivity. J. Mater. Chem. C 5, 6954-6961 (2017).
43.
Z. Huang, H. Chen, S. Xu, L.Y. Chen, Y. Huang et al., Graphene-based composites combining both excellent terahertz shielding and stealth performance. Adv. Opt. Mater. 6, 1801165 (2018).
44.
A. Iqbal, F. Shahzad, K. Hantanasirisakul, M.K. Kim, J. Kwon et al., Anomalous absorption of electromagnetic waves by 2D transition metal carbonitride Ti3CNT x (MXene). Science 369, 446-450 (2020).
45.
F. Shahzad, M. Alhabeb, C.B. Hatter, B. Anasori, S. Man Hong et al., Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 353, 1137-1140 (2016).
46.
S. Venkatachalam, D. Bertin, G. Ducournau, J.F. Lampin, D. Hourlier, Kapton-derived carbon as efficient terahertz absorbers. Carbon 100, 158-164 (2016).
47.
J. Jung, H. Lee, I. Ha, H. Cho, K.K. Kim et al., Highly stretchable and transparent electromagnetic interference shielding film based on silver nanowire percolation network for wearable electronics applications. ACS Appl. Mater. Interfaces 9, 44609-44616 (2017).
48.
Z. Lin, J. Liu, W. Peng, Y. Zhu, Y. Zhao et al., Highly stable 3D Ti3C2Tx MXene-based foam architectures toward high-performance terahertz radiation shielding. ACS Nano 14, 2109-2117 (2020).
49.
C. Pavlou, M.G. Pastore Carbone, A.C. Manikas, G. Trakakis, C. Koral et al., Effective EMI shielding behaviour of thin graphene/PMMA nanolaminates in the THz range. Nat. Commun. 12, 4655 (2021).
50.
J.H. Yim, M.A. Seo, Y.H. Ahn, F. Rotermund, D.S. Kim et al., Terahertz electromagnetic interference shielding using single-walled carbon nanotube flexible films. 2008 33rd International Conference on Infrared, Millimeter and Terahertz Waves. Pasadena, CA, USA. IEEE, (2008), pp1.
51.
A. Sarycheva, A. Polemi, Y. Liu, K. Dandekar, B. Anasori et al., 2D titanium carbide (MXene) for wireless communication. Sci. Adv. 4, eaau0920 (2018).
52.
M.M. Hasan, M.M. Hossain, H.K. Chowdhury, Two-dimensional MXene-based flexible nanostructures for functional nanodevices: a review. J. Mater. Chem. A 9, 3231-3269 (2021).
53.
X. Guo, N. Li, C. Wu, X. Dai, R. Qi et al., Studying plasmon dispersion of MXene for enhanced electromagnetic absorption. Adv. Mater. 34, e2201120 (2022).
No related articles found!
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed