Achieving Ultra-Broad Microwave Absorption Bandwidth Around Millimeter-Wave Atmospheric Window Through an Intentional Manipulation on Multi-Magnetic Resonance Behavior

doi:10.1007/s40820-024-01395-4

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	Chuyang Liu
	Lu Xu
	Xueyu Xiang
	Yujing Zhang
	Li Zhou
	Bo Ouyang
	Fan Wu
	Dong-Hyun Kim
	Guangbin Ji

Abstract：

The utilization of electromagnetic waves is rapidly advancing into the millimeter-wave frequency range, posing increasingly severe challenges in terms of electromagnetic pollution prevention and radar stealth. However, existing millimeter-wave absorbers are still inadequate in addressing these issues due to their monotonous magnetic resonance pattern. In this work, rare-earth La³⁺ and non-magnetic Zr⁴⁺ ions are simultaneously incorporated into M-type barium ferrite (BaM) to intentionally manipulate the multi-magnetic resonance behavior. By leveraging the contrary impact of La³⁺ and Zr⁴⁺ ions on magnetocrystalline anisotropy field, the restrictive relationship between intensity and frequency of the multi-magnetic resonance is successfully eliminated. The magnetic resonance peak-differentiating and imitating results confirm that significant multi-magnetic resonance phenomenon emerges around 35 GHz due to the reinforced exchange coupling effect between Fe³⁺ and Fe²⁺ ions. Additionally, Mössbauer spectra analysis, first-principle calculations, and least square fitting collectively identify that additional La³⁺ doping leads to a profound rearrangement of Zr⁴⁺ occupation and thus makes the portion of polarization/conduction loss increase gradually. As a consequence, the La³⁺-Zr⁴⁺ co-doped BaM achieves an ultra-broad bandwidth of 12.5 + GHz covering from 27.5 to 40 + GHz, which holds remarkable potential for millimeter-wave absorbers around the atmospheric window of 35 GHz.

Key words： Microwave absorption Ultra-broad bandwidth M-type barium ferrite Magnetocrystalline anisotropy field Multi-magnetic resonance

收稿日期: 2024-02-08 出版日期: 2024-04-22

通讯作者: Yujing Zhang, Bo Ouyang, Guangbin Ji

引用本文:

Chuyang Liu, Lu Xu, Xueyu Xiang, Yujing Zhang, Li Zhou, Bo Ouyang, Fan Wu, Dong-Hyun Kim, Guangbin Ji. [J]. Nano-Micro Letters, 2024, 16(1): 176-.
Chuyang Liu, Lu Xu, Xueyu Xiang, Yujing Zhang, Li Zhou, Bo Ouyang, Fan Wu, Dong-Hyun Kim, Guangbin Ji. Achieving Ultra-Broad Microwave Absorption Bandwidth Around Millimeter-Wave Atmospheric Window Through an Intentional Manipulation on Multi-Magnetic Resonance Behavior. Nano-Micro Letters, 2024, 16(1): 176-.

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https://www.qk.sjtu.edu.cn/nml/CN/10.1007/s40820-024-01395-4 或 https://www.qk.sjtu.edu.cn/nml/CN/Y2024/V16/I1/176

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