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Nano-Micro Letters  2024, Vol. 16 Issue (1): 189-    DOI: 10.1007/s40820-024-01406-4
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Jingjing Liu1,2,3,4,5, Biao Shi1,2,3,4,5(), Qiaojing Xu1,2,3,4,5, Yucheng Li1,2,3,4,5, Yuxiang Li1,2,3,4,5, Pengfei Liu1,2,3,4,5, Zetong SunLi1,2,3,4,5, Xuejiao Wang1,2,3,4,5, Cong Sun1,2,3,4,5, Wei Han1,2,3,4,5, Diannan Li1,2,3,4,5, Sanlong Wang1,2,3,4,5, Dekun Zhang1,2,3,4,5, Guangwu Li6,7, Xiaona Du1,2,3,4,5, Ying Zhao1,2,3,4,5, Xiaodan Zhang1,2,3,4,5()
Textured Perovskite/Silicon Tandem Solar Cells Achieving Over 30% Efficiency Promoted by 4-Fluorobenzylamine Hydroiodide
Jingjing Liu1,2,3,4,5, Biao Shi1,2,3,4,5(), Qiaojing Xu1,2,3,4,5, Yucheng Li1,2,3,4,5, Yuxiang Li1,2,3,4,5, Pengfei Liu1,2,3,4,5, Zetong SunLi1,2,3,4,5, Xuejiao Wang1,2,3,4,5, Cong Sun1,2,3,4,5, Wei Han1,2,3,4,5, Diannan Li1,2,3,4,5, Sanlong Wang1,2,3,4,5, Dekun Zhang1,2,3,4,5, Guangwu Li6,7, Xiaona Du1,2,3,4,5, Ying Zhao1,2,3,4,5, Xiaodan Zhang1,2,3,4,5()
1 Renewable Energy Conversion and Storage Center, Solar Energy Conversion Center, Institute of Photoelectronic Thin Film Devices and Technology, Nankai University, Tianjin, 300350, People’s Republic of China
2 Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Tianjin, 300350, People’s Republic of China
3 Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300192, People’s Republic of China
4 Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin, 300350, People’s Republic of China
5 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, People’s Republic of China
6 Center of Single-Molecule Sciences, Institute of Modern Optics, Tianjin Key Laboratory of Micro-Scale Optical Information Science and Technology, College of Electronic Information and Optical Engineering, Nankai University, 38 Tongyan Road, Jinnan District, Tianjin, 300350, People’s Republic of China
7 Shenzhen Research Institute of Nankai University, 16Th Floor, Yantian Science and Technology Building, Haishan Street, Yantian District, Shenzhen, 518083, People’s Republic of China
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Jingjing Liu
Biao Shi
Qiaojing Xu
Yucheng Li
Yuxiang Li
Pengfei Liu
Zetong SunLi
Xuejiao Wang
Cong Sun
Wei Han
Diannan Li
Sanlong Wang
Dekun Zhang
Guangwu Li
Xiaona Du
Ying Zhao
Xiaodan Zhang
Abstract：

Monolithic textured perovskite/silicon tandem solar cells (TSCs) are expected to achieve maximum light capture at the lowest cost, potentially exhibiting the best power conversion efficiency. However, it is challenging to fabricate high-quality perovskite films and preferred crystal orientation on commercially textured silicon substrates with micrometer-size pyramids. Here, we introduced a bulky organic molecule (4-fluorobenzylamine hydroiodide (F-PMAI)) as a perovskite additive. It is found that F-PMAI can retard the crystallization process of perovskite film through hydrogen bond interaction between F− and FA+ and reduce (111) facet surface energy due to enhanced adsorption energy of F-PMAI on the (111) facet. Besides, the bulky molecular is extruded to the bottom and top of perovskite film after crystal growth, which can passivate interface defects through strong interaction between F-PMA+ and undercoordinated Pb2+/I−. As a result, the additive facilitates the formation of large perovskite grains and (111) preferred orientation with a reduced trap-state density, thereby promoting charge carrier transportation, and enhancing device performance and stability. The perovskite/silicon TSCs achieved a champion efficiency of 30.05% based on a silicon thin film tunneling junction. In addition, the devices exhibit excellent long-term thermal and light stability without encapsulation. This work provides an effective strategy for achieving efficient and stable TSCs.
Key words： Perovskite crystallization    (111) preferred orientation    Defect passivation    Perovskite/silicon tandem solar cells
收稿日期: 2024-01-22      出版日期: 2024-05-02
通讯作者: Biao Shi, Xiaodan Zhang   
引用本文:   
Jingjing Liu, Biao Shi, Qiaojing Xu, Yucheng Li, Yuxiang Li, Pengfei Liu, Zetong SunLi, Xuejiao Wang, Cong Sun, Wei Han, Diannan Li, Sanlong Wang, Dekun Zhang, Guangwu Li, Xiaona Du, Ying Zhao, Xiaodan Zhang. [J]. Nano-Micro Letters, 2024, 16(1): 189-.
Jingjing Liu, Biao Shi, Qiaojing Xu, Yucheng Li, Yuxiang Li, Pengfei Liu, Zetong SunLi, Xuejiao Wang, Cong Sun, Wei Han, Diannan Li, Sanlong Wang, Dekun Zhang, Guangwu Li, Xiaona Du, Ying Zhao, Xiaodan Zhang. Textured Perovskite/Silicon Tandem Solar Cells Achieving Over 30% Efficiency Promoted by 4-Fluorobenzylamine Hydroiodide. Nano-Micro Letters, 2024, 16(1): 189-.
链接本文:  
https://www.qk.sjtu.edu.cn/nml/CN/10.1007/s40820-024-01406-4      或      https://www.qk.sjtu.edu.cn/nml/CN/Y2024/V16/I1/189
Fig. 1  
Fig. 2  
Fig. 3  
Fig. 4  
Sample Scan direction Voc (V) Jsc (mA cm−2) FF (%) PCE (%) SPO (%) HI (%)
w/o Rev. 1.10 22.65 77.43 19.38 18.6 7
For. 1.09 22.66 72.15 17.95
w F-PMAI Rev. 1.15 22.77 85.48 22.74 21.2 2
For. 1.14 22.82 83.00 22.07
Table 1  
Fig. 5  
Sample Scan direction Voc (V) Jsc (mA cm−2) FF (%) PCE (%) HI (%)
w/o Rev. 1.77 19.32 80.11 27.61 13
For. 1.77 19.33 69.69 24.01
w F-PMAI Rev. 1.81 20.01 82.91 30.05 2
For. 1.82 19.91 80.63 29.32
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