MXene Hollow Spheres Supported by a C-Co Exoskeleton Grow MWCNTs for Efficient Microwave Absorption

doi:10.1007/s40820-024-01326-3

Abstract

Abstract:

High-performance microwave absorption (MA) materials must be studied immediately since electromagnetic pollution has become a problem that cannot be disregarded. A straightforward composite material, comprising hollow MXene spheres loaded with C-Co frameworks, was prepared to develop multiwalled carbon nanotubes (MWCNTs). A high impedance and suitable morphology were guaranteed by the C-Co exoskeleton, the attenuation ability was provided by the MWCNTs endoskeleton, and the material performance was greatly enhanced by the layered core-shell structure. When the thickness was only 2.04 mm, the effective absorption bandwidth was 5.67 GHz, and the minimum reflection loss (RL_min) was −-70.70 dB. At a thickness of 1.861 mm, the sample calcined at 700 °C had a RL_min of −-63.25 dB. All samples performed well with a reduced filler ratio of 15 wt%. This paper provides a method for making lightweight core-shell composite MA materials with magnetoelectric synergy.

Key words: MXene, C-Co skeleton, MWCNTs, Microwave absorption

Ze Wu, Xiuli Tan, Jianqiao Wang, Youqiang Xing, Peng Huang, Bingjue Li, Lei Liu. MXene Hollow Spheres Supported by a C-Co Exoskeleton Grow MWCNTs for Efficient Microwave Absorption[J]. Nano-Micro Letters, 2024, 16(1): 107-.

Ze Wu, Xiuli Tan, Jianqiao Wang, Youqiang Xing, Peng Huang, Bingjue Li, Lei Liu. [J]. Nano-Micro Letters, 2024, 16(1): 107-.

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URL: https://www.qk.sjtu.edu.cn/nml/EN/10.1007/s40820-024-01326-3

https://www.qk.sjtu.edu.cn/nml/EN/Y2024/V16/I1/107

Figures/Tables 7

Fig. 1 Schematic illustration of the synthetic process for the HMCCo absorber

Fig. 2 SEM images of a PS, b PS@MXene, c PS@MXene@ZIF67, and d HMCCo-2. e SEM images of an open HMCCo-2 spherical shell and the internal structure of the spherical shell. f Elemental mappings of HMCCo-2. g TEM image of the edge of the sample fragments obtained after ultrasonication, including carbon nanotubes grown in situ. h TEM image of a single carbon nanotube separated by ultrasound. i HRTEM image corresponding to the white circle in (h)

Fig. 3 a XRD patterns for ZIF67, PS, PM, PMZ-2, and HMCCo-2. b Raman spectra of PS, MXene, PM, PMZ-2, and HMCCo-2. c XPS survey. d C 1s spectra of PMZ-2 and HMCCo-2. e Ti 2p spectra of PMZ-2 and HMCCo-2. f Co 2p spectra of PMZ-2 and HMCCo-2

Fig. 4 a Real and b imaginary parts of the complex permittivity, c dielectric loss tangent values, d real and e imaginary parts of the permeability, and f magnetic loss tangent values for HMCCo-1, HMCCo-2, HMCCo-3, and HMCCo-4

Fig. 5 3D reflection losses of a HMCCo-1, b HMCCo-2, c HMCCo-3, and d HMCCo-4. e Reflection losses with matching thicknesses of the HMCCo samples. f EABs of the HMCCo series

Fig. 6 RL plots for a HMCCo-400, b HMCCo-500, c HMCCo-600, d HMCCo-700, and e HMCCo-800 at thicknesses of 1 to 5 mm. f RL curves for samples prepared at different calcination temperatures with matched thicknesses. SEM images of g1 HMCCo-400, h1 HMCCo-500, i1 HMCCo-600, j1 HMCCo-700, and k1 HMCCo-800. SEM detail images of g2 HMCCo-400, h2 HMCCo-500, i2 HMCCo-600, j2 HMCCo-700, and k2 HMCCo-800

Fig. 7 Mechanism for electromagnetic wave loss

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