In recent years, with the rapid development of technology, the application of USV technology in the military field has gradually become one of the focuses of international military competition. In the Russo Ukrainian War, the USV maritime combat mode has shown new breakthroughs, providing new ideas and possibilities for future maritime operations. This article explores the application value, technical characteristics, and future development trends of unmanned vessels in maritime operations during the Russo Ukrainian War through practical case analysis. The aim is to provide reference and inspiration for research and practice in related fields.